Investigation of Platinum-Group Minerals (PGM) from Othrys Chromitites (Greece) Using Superpanning Concentrates

Platinum-group minerals were concentrated using superpanning from two composite chromitite samples, which were collected from two old mines within the Othrys ophiolite. This method allows for the recovery of a broad spectrum of these rare and fine-grained minerals, and helps to better identify them and interpret their origin. Major differences between the east and west Othrys ophiolites were determined, probably as a result of their different origin and evolution. Primary Os-, Ir-, and Ru-bearing platinum-group minerals (IPGM)-alloys and the Rh-, Pt- and Pd-bearing platinum-group minerals (PPGM) occur only in the east Othrys chromitite, indicating an evolution from initially low fS2 conditions at shallower mantle levels with the subsequent implication of a S-saturated ascending fluid. In contrast, the absence of primary IPGM-alloys in west Othrys chromitite indicates that S saturation had been attained. The presence of erlichmanite suggests that sulphur fugacity eventually increased significantly in both suites. Substantial fluctuations of a fluid phase, likely related to serpentinising fluids, modified the platinum-group minerals (PGM) assemblage of west Othrys, and resulted in a large diversity of secondary PGM minerals. The limited number of secondary species developed in the east Othrys indicate that secondary processes were also different in the two suites.