The effect of staging of reburning fuel to reduce NO{sub x} and N{sub 2}O levels during fluidized bed coal combustion
I. Gulyurtlu, Carlos Bordalo, I. Cabrita
Abstract
I. Gulyurtlu, Carlos Bordalo, I. Cabrita
Abstract
Studies have been undertaken with the objective of using biomass waste as a reburning fuel which could be introduced to the combustor at different heights. The staging of the secondary air was also implemented as a further measure for controlling the emissions of NO{sub x} and N{sub 2}O. The biomass waste contains very high volatile content and very small amounts of fuel-N. Upon release, these volatiles are generally released as NH{sub y} compounds rather than HCN or other CN groups. Consequently, the reactions leading to the formation of both N{sub 2}O and NO{sub x} appear to be suppressed and the presence of high levels of hydrocarbon radicals originating from volatiles consequently gives rise to a reduction in NO{sub x} amounts. Experimental results obtained suggest that the N{sub 2}O amounts could be lowered by about 20 to 40% and NO{sub x} values were found to be brought down below 250 ppm. With only coal combustion the levels of NO{sub x} and N{sub 2}O were measured to be about 400 and 100 ppm respectively. No adverse effects on SO{sub 2} capture were observed.
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Studies have been undertaken with the objective of using biomass waste as a reburning fuel which could be introduced to the combustor at different heights. The staging of the secondary air was also implemented as a further measure for controlling the emissions of NO{sub x} and N{sub 2}O. The biomass waste contains very high volatile content and very small amounts of fuel-N. Upon release, these volatiles are generally released as NH{sub y} compounds rather than HCN or other CN groups. Consequently, the reactions leading to the formation of both N{sub 2}O and NO{sub x} appear to be suppressed and the presence of high levels of hydrocarbon radicals originating from volatiles consequently gives rise to a reduction in NO{sub x} amounts. Experimental results obtained suggest that the N{sub 2}O amounts could be lowered by about 20 to 40% and NO{sub x} values were found to be brought down below 250 ppm. With only coal combustion the levels of NO{sub x} and N{sub 2}O were measured to be about 400 and 100 ppm respectively. No adverse effects on SO{sub 2} capture were observed.
Key concepts: Combustion, Coal, Combustor, Chemistry, Fluidized bed combustion, Hydrocarbon, Staged combustion, Coal combustion products