2005RWTH Publications (RWTH Aachen)Requires access

Critics of non-isothermal kinetic methods to calculate the kinetic parameters

C. Popescu, E. Segal, C. Popescu

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Abstract

By surveying the most used methods for evaluating the kinetic parameters from non-isothermal measurements, we propose their classification scheme. As a result of the analysis we suggest a methodology to analyse the data from non-isothermal experiments and discuss several problems of non-isothcnnal kinetics, e.g., the validity of steady-state approximation under non-isothermal conditions and the problem of expressing the activation energy as a range of values.

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What this paper is about

By surveying the most used methods for evaluating the kinetic parameters from non-isothermal measurements, we propose their classification scheme. As a result of the analysis we suggest a methodology to analyse the data from non-isothermal experiments and discuss several problems of non-isothcnnal kinetics, e.g., the validity of steady-state approximation under non-isothermal conditions and the problem of expressing the activation energy as a range of values.

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Available abstract

By surveying the most used methods for evaluating the kinetic parameters from non-isothermal measurements, we propose their classification scheme. As a result of the analysis we suggest a methodology to analyse the data from non-isothermal experiments and discuss several problems of non-isothcnnal kinetics, e.g., the validity of steady-state approximation under non-isothermal conditions and the problem of expressing the activation energy as a range of values.

Key concepts: Isothermal process, Kinetic energy, Thermodynamics, Range (aeronautics), Kinetics, Activation energy, Kinetic scheme, Materials science

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