Critics of non-isothermal kinetic methods to calculate the kinetic parameters
C. Popescu, E. Segal, C. Popescu
Abstract
C. Popescu, E. Segal, C. Popescu
Abstract
By surveying the most used methods for evaluating the kinetic parameters from non-isothermal measurements, we propose their classification scheme. As a result of the analysis we suggest a methodology to analyse the data from non-isothermal experiments and discuss several problems of non-isothcnnal kinetics, e.g., the validity of steady-state approximation under non-isothermal conditions and the problem of expressing the activation energy as a range of values.
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By surveying the most used methods for evaluating the kinetic parameters from non-isothermal measurements, we propose their classification scheme. As a result of the analysis we suggest a methodology to analyse the data from non-isothermal experiments and discuss several problems of non-isothcnnal kinetics, e.g., the validity of steady-state approximation under non-isothermal conditions and the problem of expressing the activation energy as a range of values.
Key concepts: Isothermal process, Kinetic energy, Thermodynamics, Range (aeronautics), Kinetics, Activation energy, Kinetic scheme, Materials science