Novel Poly(imide—siloxane) Polymers and Copolymers
F. L. Keohan, John E. Hallgren
Abstract
F. L. Keohan, John E. Hallgren
Abstract
The synthesis and properties of poly(imide—siloxane) polymers and copolymers based on 5,5′-bis(1,1,3,3-tetramethyl-1,3-disiloxanediyl) norbornane dicarboxylic anhydride are described. High-molecular-weight thermoplastics and elastoplastics were prepared readily in solution from aromatic diamines, organic dianhydrides, and this unique anhydride-terminated siloxane. The thermal and mechanical properties of a variety of copolymer compositions are described. Average siloxane block length and overall siloxane content had the greatest effect on these properties.
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The synthesis and properties of poly(imide—siloxane) polymers and copolymers based on 5,5′-bis(1,1,3,3-tetramethyl-1,3-disiloxanediyl) norbornane dicarboxylic anhydride are described. High-molecular-weight thermoplastics and elastoplastics were prepared readily in solution from aromatic diamines, organic dianhydrides, and this unique anhydride-terminated siloxane. The thermal and mechanical properties of a variety of copolymer compositions are described. Average siloxane block length and overall siloxane content had the greatest effect on these properties.
Key concepts: Siloxane, Copolymer, Imide, Materials science, Polymer, Polymer chemistry, Organic chemistry, Composite material