1989•Advances in chemistry seriesRequires access

Novel Poly(imide—siloxane) Polymers and Copolymers

F. L. Keohan, John E. Hallgren

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Abstract

The synthesis and properties of poly(imide—siloxane) polymers and copolymers based on 5,5′-bis(1,1,3,3-tetramethyl-1,3-disiloxanediyl) norbornane dicarboxylic anhydride are described. High-molecular-weight thermoplastics and elastoplastics were prepared readily in solution from aromatic diamines, organic dianhydrides, and this unique anhydride-terminated siloxane. The thermal and mechanical properties of a variety of copolymer compositions are described. Average siloxane block length and overall siloxane content had the greatest effect on these properties.

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The synthesis and properties of poly(imide—siloxane) polymers and copolymers based on 5,5′-bis(1,1,3,3-tetramethyl-1,3-disiloxanediyl) norbornane dicarboxylic anhydride are described. High-molecular-weight thermoplastics and elastoplastics were prepared readily in solution from aromatic diamines, organic dianhydrides, and this unique anhydride-terminated siloxane. The thermal and mechanical properties of a variety of copolymer compositions are described. Average siloxane block length and overall siloxane content had the greatest effect on these properties.

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Available abstract

The synthesis and properties of poly(imide—siloxane) polymers and copolymers based on 5,5′-bis(1,1,3,3-tetramethyl-1,3-disiloxanediyl) norbornane dicarboxylic anhydride are described. High-molecular-weight thermoplastics and elastoplastics were prepared readily in solution from aromatic diamines, organic dianhydrides, and this unique anhydride-terminated siloxane. The thermal and mechanical properties of a variety of copolymer compositions are described. Average siloxane block length and overall siloxane content had the greatest effect on these properties.

Key concepts: Siloxane, Copolymer, Imide, Materials science, Polymer, Polymer chemistry, Organic chemistry, Composite material

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