ScholarLens Back to search
2002•Zeitschrift für Naturforschung BRequires access

A Pyrazine-Bridged Ni(II) Coordination Polymer

Chirantan Roy Choudhury, S.K. Dey, Sutapa Sen, Bappaditya Bag, Samiran Mitra, Völker Gramlich

Open publisher page 12 citations

Abstract

The single pyrazine-bridged polymeric complex {[Ni(pyz)(H2O)4](NO3)2.2H2O}n has been synthesised and characterised by elemental analyses, IR and UV-vis spectra, and a single-crystal X-ray diffraction study. The coordination around the Ni centre is perfectly octahedral. The Ni(H2O)4 coordination planes are bridged by pyrazine ligands forming an infinite chain structure. Two nitrate anions and two water molecules exist in the lattice and are linked by intermolecular hydrogen bonds to the coordinated water molecules.

About this research paper

What this paper is about

The single pyrazine-bridged polymeric complex {[Ni(pyz)(H2O)4](NO3)2.2H2O}n has been synthesised and characterised by elemental analyses, IR and UV-vis spectra, and a single-crystal X-ray diffraction study. The coordination around the Ni centre is perfectly octahedral. The Ni(H2O)4 coordination planes are bridged by pyrazine ligands forming an infinite chain structure. Two nitrate anions and two water molecules exist in the lattice and are linked by intermolecular hydrogen bonds to the coordinated water molecules.

Why it matters

OpenAlex reports 12 citations for this work. Citation counts describe recorded attention and do not establish research quality.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

The single pyrazine-bridged polymeric complex {[Ni(pyz)(H2O)4](NO3)2.2H2O}n has been synthesised and characterised by elemental analyses, IR and UV-vis spectra, and a single-crystal X-ray diffraction study. The coordination around the Ni centre is perfectly octahedral. The Ni(H2O)4 coordination planes are bridged by pyrazine ligands forming an infinite chain structure. Two nitrate anions and two water molecules exist in the lattice and are linked by intermolecular hydrogen bonds to the coordinated water molecules.

Key concepts: Pyrazine, Coordination polymer, Hydrogen bond, Crystallography, Molecule, Intermolecular force, Octahedron, Crystal structure

Related papers

Related paper 1Related paper 2
Back to paper searchBrowse research topicsOriginal source
A Pyrazine-Bridged Ni(II) Coordination Polymer — Research Paper | ScholarLens