(+)-Sparteine N-16-oxide, a lupin alkaloid from Lygos raetam var. sarcocarpa.
Abdel-Halim Ob, Fattah Ha, A F Halim, Isamu Murakoshi
Abstract
Abdel-Halim Ob, Fattah Ha, A F Halim, Isamu Murakoshi
Abstract
A new lupin alkaloid, (+)-sparteine N-16-oxide was isolated from Lygos raetam var. sarcocarpa, together with five known alkaloids: (+)-aphylline, (+)-17 oxosparteine, (-)-5,6-dehydrolupanine, (-)-N-formyl cytisine and (+)-ammodenderine. The structure of the new alkaloid including absolute configuration was determined by spectroscopic methods and chemical transformation.
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A new lupin alkaloid, (+)-sparteine N-16-oxide was isolated from Lygos raetam var. sarcocarpa, together with five known alkaloids: (+)-aphylline, (+)-17 oxosparteine, (-)-5,6-dehydrolupanine, (-)-N-formyl cytisine and (+)-ammodenderine. The structure of the new alkaloid including absolute configuration was determined by spectroscopic methods and chemical transformation.
Key concepts: Sparteine, Alkaloid, Cytisine, Chemistry, Stereochemistry, Biochemistry, Receptor, Nicotinic agonist