The Reaction of Enamine with Amide·Phosphorylchloride Complex and the Reduction of Enamine

2-Acylcyclohexanones (IV and V) are obtained from the reaction of amide-POCl3 complexes (II and III) with enamine (I), while the lactam-condensed products (VIII and XII) or enamine-reduced products (XI and XIV) are obtained from the reaction of lactam-POCl3 complexes (VI and X) with enamines (I or XIII).