ChemInform Abstract: Reactions of Unsymmetrical λ5P‐λ3P Diphosphorus Compounds and of Diphosphines (λ3P‐λ3P) with o‐Quinones.
Johannes Breker, R. Schmutzler, Bernd Dorbath, M. Wieber
Abstract
Johannes Breker, R. Schmutzler, Bernd Dorbath, M. Wieber
Abstract
Abstract The reaction of the diphosphorus compounds (I) with the o‐benzoquinone (II) leads to oxidative addition of (II) to give λ3P and also to insertion of a further molecule of (II) into the P‐P bond to give the catecholate products (III).
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Abstract The reaction of the diphosphorus compounds (I) with the o‐benzoquinone (II) leads to oxidative addition of (II) to give λ3P and also to insertion of a further molecule of (II) into the P‐P bond to give the catecholate products (III).
Key concepts: Chemistry, Diphosphines, Medicinal chemistry, Oxidative addition, Benzoquinone, Molecule, Photochemistry, Organic chemistry