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ChemInform Abstract: New Access to Cyclopentane Derivatives. A Radical Chain Reaction.

Klaus Weinges, Wolfgang Sipos

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Abstract

Abstract The reaction of the ester (V) (obtained starting from the hydroxytetrahydropyrane (I) via the intermediate (III)) with Hg(O‐Ac)2 in the presence of CaO and MeOH (VI) followed by reduction affords a cis‐trans mixture of the cyclopentane derivatives (VII).

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What this paper is about

Abstract The reaction of the ester (V) (obtained starting from the hydroxytetrahydropyrane (I) via the intermediate (III)) with Hg(O‐Ac)2 in the presence of CaO and MeOH (VI) followed by reduction affords a cis‐trans mixture of the cyclopentane derivatives (VII).

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Available abstract

Abstract The reaction of the ester (V) (obtained starting from the hydroxytetrahydropyrane (I) via the intermediate (III)) with Hg(O‐Ac)2 in the presence of CaO and MeOH (VI) followed by reduction affords a cis‐trans mixture of the cyclopentane derivatives (VII).

Key concepts: Chemistry, Cyclopentane, Medicinal chemistry, Chain (unit), Organic chemistry, Astronomy, Physics

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