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ChemInform Abstract: Formation of Unsaturated Acyclic Ketones in the Complex‐Catalyzed Telomerization of Isoprene in Acetone.

Rüdiger Berger, Bettina Franke, Walter Gaube, Manfred Helms

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Abstract

Abstract Isoprene reacts in the presence of Pd‐complexes + phosphines in acetone/H2O under pressure (Pd:P:(I):(II):H2O:CO2 = 1:3:200:550:130:50) to give dimers, dimethyloctadienols, and unsaturated ketones of molecular mass 194; one of the two main ketones is identified to be (III).

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What this paper is about

Abstract Isoprene reacts in the presence of Pd‐complexes + phosphines in acetone/H2O under pressure (Pd:P:(I):(II):H2O:CO2 = 1:3:200:550:130:50) to give dimers, dimethyloctadienols, and unsaturated ketones of molecular mass 194; one of the two main ketones is identified to be (III).

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Available abstract

Abstract Isoprene reacts in the presence of Pd‐complexes + phosphines in acetone/H2O under pressure (Pd:P:(I):(II):H2O:CO2 = 1:3:200:550:130:50) to give dimers, dimethyloctadienols, and unsaturated ketones of molecular mass 194; one of the two main ketones is identified to be (III).

Key concepts: Isoprene, Chemistry, Telomerization, Acetone, Ketone, Catalysis, Organic chemistry, Medicinal chemistry

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ChemInform Abstract: Formation of Unsaturated Acyclic Ketones in the Complex‐Catalyzed Telomerization of Isoprene in Acetone. — Research Paper | ScholarLens