Temperature dependences of saturated vapor pressure and the enthalpy of vaporization of n-pentyl esters of dicarboxylic acids
Svetlana V. Portnova, E. L. Krasnykh, С. В. Леванова
Abstract
Svetlana V. Portnova, E. L. Krasnykh, С. В. Леванова
Abstract
The saturated vapor pressures and enthalpies of vaporization of n -pentyl esters of linear С 2 –С 6 dicarboxylic acids are determined by the transpiration method in the temperature range of 309.2–361.2 K. The dependences of enthalpies of vaporization on the number of carbon atoms in the molecule and on the retention indices have been determined. The predictive capabilities of the existing calculation schemes for estimation of enthalpy of vaporization of the studied compounds have been analyzed.
OpenAlex reports 4 citations for this work. Citation counts describe recorded attention and do not establish research quality.
A contribution statement is not available in the OpenAlex record.
Method details are not available in the OpenAlex metadata.
Findings are not separately available in the OpenAlex metadata.
Limitations are not available in the OpenAlex metadata.
Application details are not available in the OpenAlex metadata.
The saturated vapor pressures and enthalpies of vaporization of n -pentyl esters of linear С 2 –С 6 dicarboxylic acids are determined by the transpiration method in the temperature range of 309.2–361.2 K. The dependences of enthalpies of vaporization on the number of carbon atoms in the molecule and on the retention indices have been determined. The predictive capabilities of the existing calculation schemes for estimation of enthalpy of vaporization of the studied compounds have been analyzed.
Key concepts: Vaporization, Enthalpy of vaporization, Vapor pressure, Chemistry, Enthalpy, Thermodynamics, Standard enthalpy of formation, Transpiration