ScholarLens Back to search
1988•ChemInformRequires access

ChemInform Abstract: Chemistry of Heteroallene and Heteroallyl Derivatives of Rhenium. Part 1. Reactivity of Mixed Carbonyl(formamido)(phosphine)rhenium(I) Complexes with RNCS (R: Ph or p‐MeC6H4) and PhNCO. Crystal Structure of the Thiazetidine Rhenium(I) Complex (Re(CO)2(PPh3)2(PhN=C(OEt)‐S)).

R. Rossi, Andrea Marchi, Adriano Duatti, Luciano Magon, Umberto Casellato, R. Graziani, Ahmed Mohamed Hussein

Open publisher page 0 citations

Abstract

Abstract The formamido‐Re(I) compound (I) reacts with an excess of PhNCS (II) to give, after treatment with EtOH (III), the new thiazetidine‐Re(I) derivatives (IV) and ‐ by formal insertion of the heterocumulene molecule into the Re‐N bond ‐ the thioureido derivative (V).

About this research paper

What this paper is about

Abstract The formamido‐Re(I) compound (I) reacts with an excess of PhNCS (II) to give, after treatment with EtOH (III), the new thiazetidine‐Re(I) derivatives (IV) and ‐ by formal insertion of the heterocumulene molecule into the Re‐N bond ‐ the thioureido derivative (V).

Why it matters

A significance statement is not available in the OpenAlex record.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

Abstract The formamido‐Re(I) compound (I) reacts with an excess of PhNCS (II) to give, after treatment with EtOH (III), the new thiazetidine‐Re(I) derivatives (IV) and ‐ by formal insertion of the heterocumulene molecule into the Re‐N bond ‐ the thioureido derivative (V).

Key concepts: Chemistry, Rhenium, Reactivity (psychology), Phosphine, Derivative (finance), Molecule, Medicinal chemistry, Crystal structure

Related papers

Related paper 1Related paper 2Related paper 3
Back to paper searchBrowse research topicsOriginal source
ChemInform Abstract: Chemistry of Heteroallene and Heteroallyl Derivatives of Rhenium. Part 1. Reactivity of Mixed Carbonyl(formamido)(phosphine)rhenium(I) Complexes with RNCS (R: Ph or p‐MeC6H4) and PhNCO. Crystal Structure of the Thiazetidine Rhenium(I) Complex (Re(CO)2(PPh3)2(PhN=C(OEt)‐S)). — Research Paper | ScholarLens