ChemInform Abstract: Chemistry of Organosilicon Compounds. Part 229. Novel Syntheses of Bis‐(trialkylsilyl)amines by Reductive Trialkylsilylation of Azo Compounds.
Mitsuo Kira, S. NAGAI, Mitsushi Nishimura, Hideki Sakurai
Abstract
Mitsuo Kira, S. NAGAI, Mitsushi Nishimura, Hideki Sakurai
Abstract
Abstract The azo compounds (I) react with the halosilanes (II) or (IV) in the presence of lithium and Lewis catalysts to yield the bissilylamines (III) and (V).
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Abstract The azo compounds (I) react with the halosilanes (II) or (IV) in the presence of lithium and Lewis catalysts to yield the bissilylamines (III) and (V).
Key concepts: Chemistry, Organosilicon, Yield (engineering), Lithium (medication), Catalysis, Organic chemistry, Lewis acids and bases, Metallurgy