ChemInform Abstract: Nitration of Fluoroethylenes with the Nitrating Mixture (HNO3+H2SO4+SO3).
Ivan V. Martynov, Viktor I. Uvarov, V. K. BREL', V. I. Anufriev, A. V. Yarkov
Abstract
Ivan V. Martynov, Viktor I. Uvarov, V. K. BREL', V. I. Anufriev, A. V. Yarkov
Abstract
Abstract Nitration of the fluoroethylenes (I), containing a CFCl fragment, with nitric acid (II) in the presence of oleum produces the halonitroacetyl fluorides (III), whereas from the ethylenes (V), (VII), and (X) with a CF2 group, the nitroethyl fluorosulfates (VI), (VIII), or (XI) are obtained predominantly.
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Abstract Nitration of the fluoroethylenes (I), containing a CFCl fragment, with nitric acid (II) in the presence of oleum produces the halonitroacetyl fluorides (III), whereas from the ethylenes (V), (VII), and (X) with a CF2 group, the nitroethyl fluorosulfates (VI), (VIII), or (XI) are obtained predominantly.
Key concepts: Oleum, Nitration, Chemistry, Nitric acid, Medicinal chemistry, Organic chemistry