ChemInform Abstract: Formation and Nitrogen NMR Spectra of Some Nitrimines (′Pernitroso‐ketones′), and the Mechanism of Oxime Cleavage by Nitrous Acid.
Spiros Adamopoulos, A. John Boulton, Rahim Tadayoni, G. A. Webb
Abstract
Spiros Adamopoulos, A. John Boulton, Rahim Tadayoni, G. A. Webb
Abstract
Abstract The formation of nitrimines, by the action of nitrous acid on oximes, is shown to proceed without scrambling of the nitrogen atoms, the oxime nitrogen forming the imine, and the nitrous acid generating the nitro group.
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Abstract The formation of nitrimines, by the action of nitrous acid on oximes, is shown to proceed without scrambling of the nitrogen atoms, the oxime nitrogen forming the imine, and the nitrous acid generating the nitro group.
Key concepts: Chemistry, Nitrous acid, Oxime, Imine, Nitrogen, Cleavage (geology), Medicinal chemistry, Organic chemistry