Biosorption kinetics of Baker's yeast in lead and copper waste water
Qunwei Dai, Faqin Dong, Mary Jane Noonan, Wei Zhang
Abstract
Qunwei Dai, Faqin Dong, Mary Jane Noonan, Wei Zhang
Abstract
The kinetics biosorption behavior of Baker's yeast in the simulation heavy metal waste water of Pb2+-Cu2+ was investigated.The autoclaved Baker's yeast was chosen as a biosorbent,and then the kinetics biosorption process and second-kinetics model were analyzed,respectively.The results show that there is very good biosorption effect at first 60 min.At the same initial concentration for heavy metal ions,there are the relations:qt(Pb2+)qt(Pb2 +-Cu2+) qt(Cu2+).The second-kinetics biosorption model's analysis shows that the biosorption speed to Pb2+ becomes rapid with the initial concentration of Cu2+ increasing,proving that there is obvious advantage to Pb2+ in the biosorption sites competition process.And the analysis results of EDS approve it also.The analysis of SEM shows that the Baker's yeast cells are broken after the biosorption of Pb2+ and Cu2+ ions.The toxicity of heavy ions to yeast cells makes the cells distort and break.The cytoplasm leaks out from the yeast cells.The biosorption of baker's yeast to Pb2+ and Cu2+ is a rapid and preferable process,and there is a more obvious advantage for Baker's yeast to Pb2+ than Cu2+.
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The kinetics biosorption behavior of Baker's yeast in the simulation heavy metal waste water of Pb2+-Cu2+ was investigated.The autoclaved Baker's yeast was chosen as a biosorbent,and then the kinetics biosorption process and second-kinetics model were analyzed,respectively.The results show that there is very good biosorption effect at first 60 min.At the same initial concentration for heavy metal ions,there are the relations:qt(Pb2+)qt(Pb2 +-Cu2+) qt(Cu2+).The second-kinetics biosorption model's analysis shows that the biosorption speed to Pb2+ becomes rapid with the initial concentration of Cu2+ increasing,proving that there is obvious advantage to Pb2+ in the biosorption sites competition process.And the analysis results of EDS approve it also.The analysis of SEM shows that the Baker's yeast cells are broken after the biosorption of Pb2+ and Cu2+ ions.The toxicity of heavy ions to yeast cells makes the cells distort and break.The cytoplasm leaks out from the yeast cells.The biosorption of baker's yeast to Pb2+ and Cu2+ is a rapid and preferable process,and there is a more obvious advantage for Baker's yeast to Pb2+ than Cu2+.
Key concepts: Biosorption, Yeast, Kinetics, Copper, Nuclear chemistry, Metal, Chemistry, Metal ions in aqueous solution