Synthesis and Crystal Structure of Ternary Complex of Cu(II) with 1,10-Phenanthroline and L-α-Phenylalanine

The ternary complex of Cu(Ⅱ) with 1,10-phenanthroline(phen) and L-α-phenylalanine(L-phe) was prepared and characterized by elemental analysis,IR and X-ray crystal diffraction analysis.The crystal belongs to monoclinic system,space group P2(1),with a=0.584 92(2) nm,b= 2.038 04(5) nm,c= 0.966 68(3) nm,α= 90°,β= 94.276(2)°,γ= 90°,V= 1.149 16(6) nm~(3),Z= 2,M_(r)= 529.90,Dc = 1.531 Mg/m~(3),F(000) =543,μ=1.113 mm~(-1),S= 1.045,R_(1)= 0.047 7,wR_(2)= 0.130 8.