Effect of Pentose Stereo-Isomerization on the Formation of Volatiles in the Reaction System of Pentose/Cysteine
Hou Ya-long, Zhengxing Chen, Luo Chang-rong, Wang Guang-yu
Abstract
Hou Ya-long, Zhengxing Chen, Luo Chang-rong, Wang Guang-yu
Abstract
The type and relative content of volatile substances formed in the reaction system of different pentose/cysteine were determined by HS-SPME method combined with GC/MS.The relationship between pentose structure and reaction activity was analyzed and compared.Pentose and L-cysteine dissolved in the sodium phosphate buffer(0.2 mol/L,pH 5) at equal molar concentration(0.4 mol/L),when the reaction time is 40 minute at 120 ℃,the volatiles quantity of ribose was higher than that of the others.This results demonstrated that the Maillard reaction activity of ribose was the highest.After reacting 3 hours,the volatiles production of four pentose was equally.
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The type and relative content of volatile substances formed in the reaction system of different pentose/cysteine were determined by HS-SPME method combined with GC/MS.The relationship between pentose structure and reaction activity was analyzed and compared.Pentose and L-cysteine dissolved in the sodium phosphate buffer(0.2 mol/L,pH 5) at equal molar concentration(0.4 mol/L),when the reaction time is 40 minute at 120 ℃,the volatiles quantity of ribose was higher than that of the others.This results demonstrated that the Maillard reaction activity of ribose was the highest.After reacting 3 hours,the volatiles production of four pentose was equally.
Key concepts: Pentose, Chemistry, Maillard reaction, Ribose, Pentose phosphate pathway, Cysteine, Isomerization, Biochemistry