2006Huagong jinzhanRequires access

Advances in techniques for production of cyclohexanone and cyclohexanol

Tong Ze-min

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Abstract

The technical progress of producing cyclohexanone and cyclohexanol is reviewed.Two commercial routes to produce cyclohexanone and cyclohexanol are introduced:(1)Oxidation of cyclohexane to cyclohexanone and cyclohexanol;(2) Hydration of cyclohexene to cyclohexanol.Recent developments in oxidation of cyclohexane are described in detail,especially the catalysts.The catalysts include photooxidation catalyst,nanostructured catalyst,Gif catalyst,bionic catalyst,zeolite catalyst and composite catalyst.The researches on commercial production of cyclohexanone and cyclohexanol are discussed.

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What this paper is about

The technical progress of producing cyclohexanone and cyclohexanol is reviewed.Two commercial routes to produce cyclohexanone and cyclohexanol are introduced:(1)Oxidation of cyclohexane to cyclohexanone and cyclohexanol;(2) Hydration of cyclohexene to cyclohexanol.Recent developments in oxidation of cyclohexane are described in detail,especially the catalysts.The catalysts include photooxidation catalyst,nanostructured catalyst,Gif catalyst,bionic catalyst,zeolite catalyst and composite catalyst.The researches on commercial production of cyclohexanone and cyclohexanol are discussed.

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Available abstract

The technical progress of producing cyclohexanone and cyclohexanol is reviewed.Two commercial routes to produce cyclohexanone and cyclohexanol are introduced:(1)Oxidation of cyclohexane to cyclohexanone and cyclohexanol;(2) Hydration of cyclohexene to cyclohexanol.Recent developments in oxidation of cyclohexane are described in detail,especially the catalysts.The catalysts include photooxidation catalyst,nanostructured catalyst,Gif catalyst,bionic catalyst,zeolite catalyst and composite catalyst.The researches on commercial production of cyclohexanone and cyclohexanol are discussed.

Key concepts: Cyclohexanol, Cyclohexanone, Cyclohexane, Catalysis, Cyclohexene, Zeolite, Organic chemistry, Chemistry

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