ChemInform Abstract: Oxygen Atom Transfer in the Oxidation of Triphenylphosphine by Molecular Oxygen Catalyzed by an Ru(III)‐ EDTA ‐ PPh3 Complex.
M.M.Taqui Khán, Mohammed Rafiq H. Siddiqui, Amjad Hussain, M. A. Moiz
Abstract
M.M.Taqui Khán, Mohammed Rafiq H. Siddiqui, Amjad Hussain, M. A. Moiz
Abstract
Abstract The oxidation of PPh3 to O = PPh3 in the presence of a Ru(III) ‐ EDTA complex, and molecular oxygen in dioxane/water proceeds through the formation of the intermediate complexes (I), (II) and the dimeric p‐peroxo compound (III).
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Abstract The oxidation of PPh3 to O = PPh3 in the presence of a Ru(III) ‐ EDTA complex, and molecular oxygen in dioxane/water proceeds through the formation of the intermediate complexes (I), (II) and the dimeric p‐peroxo compound (III).
Key concepts: Triphenylphosphine, Molecular oxygen, Oxygen atom, Chemistry, Oxygen, Catalysis, Medicinal chemistry, Atom (system on chip)