Colour Reaction of Chromogenic Reagent 3,5-Di-bromine-2-pyridinediazoaminoazobenzene with Cadmium(II) and its Application
Meng Shuang, Pan Jiao
Abstract
Meng Shuang, Pan Jiao
Abstract
Synthesis of a new reagent 3,5 di bromine 2 pyridinediazoaminoazobenzene and its chromogenic reaction with cadmium(Ⅱ) ion was repored. In a weak alkaline medium, the reagent reacted with cadmium(Ⅱ) to form a 4∶1 red complex. The absorption maximum of the complex is at 526 nm and the apparent molar absorptivity is 2.04×10 5 L·mol -1 ·cm -1 . Beer′s law is obeyed for cadmium(Ⅱ) in the range of 0~15 μg/25 mL. This method was employed to determine trace amounts of cadmium(Ⅱ) in waste water.
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Synthesis of a new reagent 3,5 di bromine 2 pyridinediazoaminoazobenzene and its chromogenic reaction with cadmium(Ⅱ) ion was repored. In a weak alkaline medium, the reagent reacted with cadmium(Ⅱ) to form a 4∶1 red complex. The absorption maximum of the complex is at 526 nm and the apparent molar absorptivity is 2.04×10 5 L·mol -1 ·cm -1 . Beer′s law is obeyed for cadmium(Ⅱ) in the range of 0~15 μg/25 mL. This method was employed to determine trace amounts of cadmium(Ⅱ) in waste water.
Key concepts: Chemistry, Reagent, Chromogenic, Molar absorptivity, Cadmium, Bromine, Color reaction, Absorption (acoustics)