2011•Wuji huaxue xuebaoRequires access

Coordination of the New Schiff Base with Copper(II) or Iron(III) in Solution

Zhu Bi

Abstract

A new Schiff base C 33 H 31 N 4 O 5(L) was synthesized from 1-(3-pyridyl)-1,3-butanedione and 1,3-bis(2-aminophenoxyl)-2-propanol.The structure of the Schiff base was determined by X-ray diffraction analysis.Furthermore,the coordination reaction of the Schiff base with Cu(Ⅱ) or Fe(Ⅲ) was investigated via UV-Vis spectroscopy,the stability constants of the two complexes were determined respectively.

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Key concepts: Schiff base, Copper, Chemistry, Coordination complex, Base (topology), Coordination number, Inorganic chemistry, Crystallography