Geochemistry of picritic and associated basalt flows of the western Emeishan flood basalt province,China:evidence for a plume-head origin.

Picritic lava flows near Lijiang in the late Permian Emeishan flood basalt province are associated with augite-phyric basalt,aphyric basalt,and pyroclastic units.The dominant phenocryst in the picritic flows is Mg-rich olivine (up to 91.6% forsterite component) with high CaO (to 0.42wt%) and glass inclusions,indicating the olivine crystallized from a melt.Associated chromite has high Cr-number (73～75).The estimated MgO content of the primitive picritic liquids is about 22wt%,and initial melt temperature may have been as high as 1630～1680℃.The basaltic lavas appear to be related to the picritic ones principally by olivine and clinopyroxene fractionation.Age-corrected Nd-Sr-Pb isotope ratios of the picritic and basaltic lavas are indistinguishable and cover a rather small range (e.g.,e_(Nd)(t)=-1.3 to+4.0).The higher-e_(Nd)(t) lavas are isotopically similar to those of several modern oceanic hotspots,and have ocean-island-like patterns of alteration-resistant incompatible elements.Heavy rare-earth element characteristics indicate an important role for garnet during melting and that the lavas were formed by rather small amounts of partial melting.Rough correlations of isotope ratios with ratios of alteration-resistant highly incompatible elements (e.g.,Nb/La) suggest minor amounts of contamination involving continental material or continental lithospheric mantle with a relatively low-e_(Nd) component in the source.Overall,our results are consistent with other evidence suggesting a plume-head origin for the Emeishan province.