2007•Chemical Research and ApplicationRequires access

Hydrothermal synthesis and structure characterization of compound (DienH_3)_2(DienH_2)[(V_8~(IV)V_(10)~V)O_(42)(PO_4)](PO_4)·H_2O

Yanmin Chen

Abstract

A mixed-valence polyoxovanadate(DienH3)2(DienH2)[(VⅣ8VⅤ10)O42(PO4)](PO4)·H2O has been hydrothermally synthesized and characterized by elemental analysis,TAG,IR, ESR and X-ray diffraction.Crystal data:monoclinic, space group C2/c,a=23.728(4),b=12.998(2) ,c=20.089(4) ,β=106.072(3)°,V=5953.4(18)3,Z=4,Dc=2.516g/cm3,C12H52N9O51P2V18,Mr=2116.99,R=0.0974,wR=0.2107(Dien=diethylenetriamine).

About this research paper

What this paper is about

Why it matters

A significance statement is not available in the OpenAlex record.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

Key concepts: Hydrothermal circulation, Characterization (materials science), Chemistry, Hydrothermal synthesis, Nuclear chemistry, Materials science, Crystallography, Chemical engineering