2003Unpublished venueRequires access

The Study of Monitoring for Reduction Process of Oxygen by Electrochemiluminescense of Luminol in Neutral Medium

Yifeng Tu

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Abstract

Based on the electrochemiluminescense,ECL)behavior of luminol in the neutral medi-um of boric acid buffer,Na 2 B 4 O 7 -H 3 BO 3 ),which was excited by the positive rectangular pulse,the enhancement of ECL from dissolved oxygen and hydro-peroxide is studied in this paper.The linear ECL response range of dissolved oxygen is from0to16mg /L and the ECL response lin-early regressed to the concentration of H 2 O 2 within the range from5.4×10 -8 mol /L to2.2×10 -7 mol /L with the detecting limit of7.1×10 -9 mol /L.Accordingly,the mechanism of enhancement of lu minol's ECL by the reductive products of oxygen was discussed and the reduction process of oxygen was monitored by using luminol's ECL.

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What this paper is about

Based on the electrochemiluminescense,ECL)behavior of luminol in the neutral medi-um of boric acid buffer,Na 2 B 4 O 7 -H 3 BO 3 ),which was excited by the positive rectangular pulse,the enhancement of ECL from dissolved oxygen and hydro-peroxide is studied in this paper.The linear ECL response range of dissolved oxygen is from0to16mg /L and the ECL response lin-early regressed to the concentration of H 2 O 2 within the range from5.4×10 -8 mol /L to2.2×10 -7 mol /L with the detecting limit of7.1×10 -9 mol /L.Accordingly,the mechanism of enhancement of lu minol's ECL by the reductive products of oxygen was discussed and the reduction process of oxygen was monitored by using luminol's ECL.

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Available abstract

Based on the electrochemiluminescense,ECL)behavior of luminol in the neutral medi-um of boric acid buffer,Na 2 B 4 O 7 -H 3 BO 3 ),which was excited by the positive rectangular pulse,the enhancement of ECL from dissolved oxygen and hydro-peroxide is studied in this paper.The linear ECL response range of dissolved oxygen is from0to16mg /L and the ECL response lin-early regressed to the concentration of H 2 O 2 within the range from5.4×10 -8 mol /L to2.2×10 -7 mol /L with the detecting limit of7.1×10 -9 mol /L.Accordingly,the mechanism of enhancement of lu minol's ECL by the reductive products of oxygen was discussed and the reduction process of oxygen was monitored by using luminol's ECL.

Key concepts: Luminol, Chemistry, Oxygen, Boric acid, Detection limit, Linear range, Limiting oxygen concentration, Excited state

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