2011•Journal of Beijing University of Chemical TechnologyRequires access

Intrinsic kinetics of lean methane catalytic combustion over a Cu-Mn/cordierite catalyst

Jia Zhang

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Abstract

Intrinsic kinetic studies of the catalytic combustion of lean methane over a Cu-Mn/cordierite catalyst have been carried out in an integral reactor under the following conditions: p=0.1 MPa,t=600-700 ℃ and feed composition y(CH4)=0.1%-1%.The kinetic model parameters were estimated by means of the Simplex optimal method.Statistical tests and residual distribution results showed that the kinetic model derived is acceptable and reliable.

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Intrinsic kinetic studies of the catalytic combustion of lean methane over a Cu-Mn/cordierite catalyst have been carried out in an integral reactor under the following conditions: p=0.1 MPa,t=600-700 ℃ and feed composition y(CH4)=0.1%-1%.The kinetic model parameters were estimated by means of the Simplex optimal method.Statistical tests and residual distribution results showed that the kinetic model derived is acceptable and reliable.

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Available abstract

Intrinsic kinetic studies of the catalytic combustion of lean methane over a Cu-Mn/cordierite catalyst have been carried out in an integral reactor under the following conditions: p=0.1 MPa,t=600-700 ℃ and feed composition y(CH4)=0.1%-1%.The kinetic model parameters were estimated by means of the Simplex optimal method.Statistical tests and residual distribution results showed that the kinetic model derived is acceptable and reliable.

Key concepts: Cordierite, Catalysis, Methane, Catalytic combustion, Kinetics, Combustion, Kinetic energy, Chemistry

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