2013•Unpublished venueRequires access
Synthesis and crystal structure of d~(10) metal based coordination polymers
Ai‐Xiang Tian
Open publisher page 0 citations
Abstract
Two new coordination polymers,[Ag(4,4-bpy)(H2PO4)]·2H2O(1) and [Cu4(L)8H4](2)(4,4′-bpy=4,4′-bipy,L=4-(imidazol-1-yl)benzoic acid),have been synthesized under hydrothermal conditions and characterized by elemental analyses,IR spectra and single crystal X-ray diffraction.Complex 1 crystallizes in the monoclinic system,space group P2/c,a=8.490 9(17) nm,b=8.728 4(17)nm,c=18.498(4)nm,β=100.99(3)°,V=1.345 8(5) nm3,Z=4,R1=0.036 2,ωR2=0.096 6.Complex 1 shows a one dimensional structure.Complex 2 crystallizes in the monoclinic system,space group C2/c,a=24.509(5) nm,b=18.957(5) nm,c=17.246(5) nm,β=119.807(5)°,V=6.953(3) nm3,Z=4,R1=0.045 5(3564),ωR2=0.151 9(6161).There are a plenty of π…π interactions in complex 2.