2006•Journal of Jilin Institute of Chemical TechnologyRequires access

Hydrothermal structures of a new organic-inorganic hybrid material [(CH_2)_5NH_2]_3[PMo_(12)O_(40)]·3[(CH_2)_5NH]

Zhou Duan-wen

Abstract

An organic-inorganic hybrid material [(CH2)5NH2]3[PMo12O40] was synthesized by hydrother-mal synthesis methods determination for the first time. The crystal structure indicates that crystallizes is in Orthorhombic system, space group Pnma, withα=2.448 6(2) nm, b= 2.120 2(3) nm,c=1.193 1(4) nm,β=90.00(°), V=6.194 2(9) nm3,Z = 4, R =0.061 1,RW=0.157 3. The compound molecule make up of four piperidines act as the counter cations which combines to the [PMo12O40]3- anion by static electric force and hydrogen bonding.

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Key concepts: Orthorhombic crystal system, Hydrothermal synthesis, Hydrothermal circulation, Hydrogen bond, Crystallography, Molecule, Crystal structure, Chemistry