2012Journal of Southwest University of Science and TechnologyRequires access

Synergistic Effects of a Novel Phosphorus-Silicon Flame Retardant with Ammonium Polyphosphate in Flame Retarded Polypropylene

Tang An-bin

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Abstract

A novel phosphorus-silicon flame retardant(EMPZR) and ammonium polyphosphate(APP) have been used to improve flame retardancy of polypropylene(PP).When the mass ratio of APP/EMPZR was 20/15,the LOI value of flame retardant PP composites was increased to 28 %,and the burning grading was reached to UL-94 V-2;polypropylene,the tensile,bending and impact strength of composites were no less than plain polypropylene.Its char residue was 21.20 % at 600 ℃ which showed by the thermogravimetry analysis(TGA) and a good synergistic effects of EMPZR with APP in the halogen-free flame retardant PP composites was proved by scanning electron microscope(SEM) and FT-IR.

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What this paper is about

A novel phosphorus-silicon flame retardant(EMPZR) and ammonium polyphosphate(APP) have been used to improve flame retardancy of polypropylene(PP).When the mass ratio of APP/EMPZR was 20/15,the LOI value of flame retardant PP composites was increased to 28 %,and the burning grading was reached to UL-94 V-2;polypropylene,the tensile,bending and impact strength of composites were no less than plain polypropylene.Its char residue was 21.20 % at 600 ℃ which showed by the thermogravimetry analysis(TGA) and a good synergistic effects of EMPZR with APP in the halogen-free flame retardant PP composites was proved by scanning electron microscope(SEM) and FT-IR.

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Available abstract

A novel phosphorus-silicon flame retardant(EMPZR) and ammonium polyphosphate(APP) have been used to improve flame retardancy of polypropylene(PP).When the mass ratio of APP/EMPZR was 20/15,the LOI value of flame retardant PP composites was increased to 28 %,and the burning grading was reached to UL-94 V-2;polypropylene,the tensile,bending and impact strength of composites were no less than plain polypropylene.Its char residue was 21.20 % at 600 ℃ which showed by the thermogravimetry analysis(TGA) and a good synergistic effects of EMPZR with APP in the halogen-free flame retardant PP composites was proved by scanning electron microscope(SEM) and FT-IR.

Key concepts: Ammonium polyphosphate, Fire retardant, Polypropylene, Materials science, Char, Ultimate tensile strength, Composite material, Thermogravimetry

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Synergistic Effects of a Novel Phosphorus-Silicon Flame Retardant with Ammonium Polyphosphate in Flame Retarded Polypropylene — Research Paper | ScholarLens