2008Hebei Chemical Engineering and IndustryRequires access

Study on the Alkylation of Isobutane with Butene in the Ionic Liquid

Dongju Zhou

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Abstract

Ionic liquid containing aluminum trichloride, pyridine and hydrogen chloride was synthesized.The alkylation of isobutane with butene in ionic liquid was investigated in an autoclave.The catalyses effect of ionic liquid and the correlative condition to the reaction was studied.The experimental results indicate that ionic liquid shows better catalytic performance.It can be used in repeated operations and keeps its stability.When losing activity, it can be regenerated by supplying aluminum trichloride.What's more, it is easy to separate the alkylation products from the ionic liquid.

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What this paper is about

Ionic liquid containing aluminum trichloride, pyridine and hydrogen chloride was synthesized.The alkylation of isobutane with butene in ionic liquid was investigated in an autoclave.The catalyses effect of ionic liquid and the correlative condition to the reaction was studied.The experimental results indicate that ionic liquid shows better catalytic performance.It can be used in repeated operations and keeps its stability.When losing activity, it can be regenerated by supplying aluminum trichloride.What's more, it is easy to separate the alkylation products from the ionic liquid.

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Available abstract

Ionic liquid containing aluminum trichloride, pyridine and hydrogen chloride was synthesized.The alkylation of isobutane with butene in ionic liquid was investigated in an autoclave.The catalyses effect of ionic liquid and the correlative condition to the reaction was studied.The experimental results indicate that ionic liquid shows better catalytic performance.It can be used in repeated operations and keeps its stability.When losing activity, it can be regenerated by supplying aluminum trichloride.What's more, it is easy to separate the alkylation products from the ionic liquid.

Key concepts: Isobutane, Ionic liquid, Alkylation, 2-Butene, Chemistry, Pyridinium, Ionic bonding, Butene

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