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How the Nature of the Chemical Bond was Revealed

Xiang Yi-he

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Abstract

The origin and forming of Pauling's valence bond theory is introduced: Lewis's electron theory of the chemical bond,heisenberg's quantum resonance concept,Heitler and London' approximate treatment of the structure of the hydrogen molecule.The valence bond theory was perfected;The properties of the electron-pair bond was proposed;The problem of the tetrahedra configuration of carbon atom was resolved;theory of hybrid bond orbitals was established.

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The origin and forming of Pauling's valence bond theory is introduced: Lewis's electron theory of the chemical bond,heisenberg's quantum resonance concept,Heitler and London' approximate treatment of the structure of the hydrogen molecule.The valence bond theory was perfected;The properties of the electron-pair bond was proposed;The problem of the tetrahedra configuration of carbon atom was resolved;theory of hybrid bond orbitals was established.

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Available abstract

The origin and forming of Pauling's valence bond theory is introduced: Lewis's electron theory of the chemical bond,heisenberg's quantum resonance concept,Heitler and London' approximate treatment of the structure of the hydrogen molecule.The valence bond theory was perfected;The properties of the electron-pair bond was proposed;The problem of the tetrahedra configuration of carbon atom was resolved;theory of hybrid bond orbitals was established.

Key concepts: Modern valence bond theory, Valence bond theory, Generalized valence bond, Orbital hybridisation, Chemical bond, Molecular orbital theory, Single bond, Three-center two-electron bond

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