Catalytic Spectrophotometric Determination of Ruthenium in Ruthenium(III) -Potassium Periodate-Dibromo-nitro-chlorophosphonazo System
Xi Liu
Abstract
Xi Liu
Abstract
A spectrophotometric method has been developed for the determination of Ruthdnium,based on their catalytic effect on potassium periodate oxidation of dibromo nitri chlorophosphonazo in H 2SO 4 medium.The optimum conditions of the reaction,thus,have been deternined.The determination limits was 0.02μg·mL -1 ,and the linear range was 0.02 0.25μg·mL -1 .The method has been applied to determine in ore with satifatery results.
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A spectrophotometric method has been developed for the determination of Ruthdnium,based on their catalytic effect on potassium periodate oxidation of dibromo nitri chlorophosphonazo in H 2SO 4 medium.The optimum conditions of the reaction,thus,have been deternined.The determination limits was 0.02μg·mL -1 ,and the linear range was 0.02 0.25μg·mL -1 .The method has been applied to determine in ore with satifatery results.
Key concepts: Potassium periodate, Periodate, Ruthenium, Chemistry, Catalysis, Potassium, Spectrophotometry, Nitro