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[Inhibitory kinetic fluorimetric determination of trace aniline].

Suling Feng, Jin Wang, Jing Fan, Fengling Cui

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Abstract

An inhibitory kinetic fluorimetric method is reported for the determination of trace aniline. The proposed method is based on the inhibitory effect of aniline on the reaction of potassium periodate oxidation of rhodamine 6G in phosphoric acid medium. The detection limit is 7.2 ng x mL(-1), the linear range of the determination is 0.010-0.183 microg x mL(-1). This method has been applied to the determination of trace aniline in phenolic tubes and water samples with satisfactory results.

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What this paper is about

An inhibitory kinetic fluorimetric method is reported for the determination of trace aniline. The proposed method is based on the inhibitory effect of aniline on the reaction of potassium periodate oxidation of rhodamine 6G in phosphoric acid medium. The detection limit is 7.2 ng x mL(-1), the linear range of the determination is 0.010-0.183 microg x mL(-1). This method has been applied to the determination of trace aniline in phenolic tubes and water samples with satisfactory results.

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Available abstract

An inhibitory kinetic fluorimetric method is reported for the determination of trace aniline. The proposed method is based on the inhibitory effect of aniline on the reaction of potassium periodate oxidation of rhodamine 6G in phosphoric acid medium. The detection limit is 7.2 ng x mL(-1), the linear range of the determination is 0.010-0.183 microg x mL(-1). This method has been applied to the determination of trace aniline in phenolic tubes and water samples with satisfactory results.

Key concepts: Aniline, Detection limit, Chemistry, Rhodamine 6G, Potassium periodate, Phosphoric acid, Linear range, Chemiluminescence

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