2002•Youtian huaxueRequires access

The Application of Oil Based Fracturing Fluids to Reservoir Stimulation at Qigequan Oil Field

She Yao

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Abstract

Two series diesel oil based and crude oil based fracturing fluids are developed for stimulating low permeable (0.001-0.03 μm 2), low temperature (25-30℃) and water sensible reservoir of Qigequan, Qinghai. In chemical structure the alkyls in phosphoric acid esters TH and XK fit to catalytic diesel oil and a crude oil taken as base oil, respectively; the crosslinker is sodium meta aluminate and is mixed all at once; the gel breaker sodium acetate is effective at low temperatures. The fluids are composed of 1.6-1.7% of phosphate TH or XK, 0.4 - 0.5% of crosslinker and 0.7-1.0% of gel breaker. The gelled fluids has viscosity 68-110 mPa·s at 30℃ (some properly formulated fluids maintain viscosity100 mPa·s after shearing at 35℃ in 30 min), break down in 12-24 hrs and give degelatinated fluids of viscosity 1.8-9.0 mPa·s, leaving a little amount of residue, and have filtrate loss coefficient C 3 ranged 1.83×10 4-6.87×10 4 m/(min) 1/2 . For hydrofracturing at Qigequan particulated pottery of density 1.56 g/cm 3 in diameter 0.45-0.90 mm is chosen as proppant. The technologic parameters of fracturing are established. The successfulness of 14 jobs performed in 2001 accounts 85.7% and the effectiveness of successful jobs-100%. The technologic parameters, designed and real, are presented for fracturing jobs in 4 wells.

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Two series diesel oil based and crude oil based fracturing fluids are developed for stimulating low permeable (0.001-0.03 μm 2), low temperature (25-30℃) and water sensible reservoir of Qigequan, Qinghai. In chemical structure the alkyls in phosphoric acid esters TH and XK fit to catalytic diesel oil and a crude oil taken as base oil, respectively; the crosslinker is sodium meta aluminate and is mixed all at once; the gel breaker sodium acetate is effective at low temperatures. The fluids are composed of 1.6-1.7% of phosphate TH or XK, 0.4 - 0.5% of crosslinker and 0.7-1.0% of gel breaker. The gelled fluids has viscosity 68-110 mPa·s at 30℃ (some properly formulated fluids maintain viscosity100 mPa·s after shearing at 35℃ in 30 min), break down in 12-24 hrs and give degelatinated fluids of viscosity 1.8-9.0 mPa·s, leaving a little amount of residue, and have filtrate loss coefficient C 3 ranged 1.83×10 4-6.87×10 4 m/(min) 1/2 . For hydrofracturing at Qigequan particulated pottery of density 1.56 g/cm 3 in diameter 0.45-0.90 mm is chosen as proppant. The technologic parameters of fracturing are established. The successfulness of 14 jobs performed in 2001 accounts 85.7% and the effectiveness of successful jobs-100%. The technologic parameters, designed and real, are presented for fracturing jobs in 4 wells.

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Available abstract

Two series diesel oil based and crude oil based fracturing fluids are developed for stimulating low permeable (0.001-0.03 μm 2), low temperature (25-30℃) and water sensible reservoir of Qigequan, Qinghai. In chemical structure the alkyls in phosphoric acid esters TH and XK fit to catalytic diesel oil and a crude oil taken as base oil, respectively; the crosslinker is sodium meta aluminate and is mixed all at once; the gel breaker sodium acetate is effective at low temperatures. The fluids are composed of 1.6-1.7% of phosphate TH or XK, 0.4 - 0.5% of crosslinker and 0.7-1.0% of gel breaker. The gelled fluids has viscosity 68-110 mPa·s at 30℃ (some properly formulated fluids maintain viscosity100 mPa·s after shearing at 35℃ in 30 min), break down in 12-24 hrs and give degelatinated fluids of viscosity 1.8-9.0 mPa·s, leaving a little amount of residue, and have filtrate loss coefficient C 3 ranged 1.83×10 4-6.87×10 4 m/(min) 1/2 . For hydrofracturing at Qigequan particulated pottery of density 1.56 g/cm 3 in diameter 0.45-0.90 mm is chosen as proppant. The technologic parameters of fracturing are established. The successfulness of 14 jobs performed in 2001 accounts 85.7% and the effectiveness of successful jobs-100%. The technologic parameters, designed and real, are presented for fracturing jobs in 4 wells.

Key concepts: Chemistry, Diesel fuel, Fracturing fluid, Petroleum engineering, Phosphoric acid, Chromatography, Chemical engineering, Organic chemistry

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