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1964•Acta Chimica SinicaRequires access

STUDIES ON ELECTRONEGATIVITY——I.THE ELECTRONEGATIVITY OF ATOMS

Huang Yuan

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Abstract

In this paper,a new electronegativity scale is proposed in terms of the atomic petcntial Χ,namely,Χ=n/r (1)where n represents the number of electrons in the valence shell of the atom and r,the covalent radius in Angstrms.The new scale is related to Pauling's electronegativity by the following equation: Χ_(Pauling)=a n/r+b (2) where a=0.34,b=0.67. The electronegativities of most elements in various valence states have been calculated and the values found are close to those obtained by other authors.

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What this paper is about

In this paper,a new electronegativity scale is proposed in terms of the atomic petcntial Χ,namely,Χ=n/r (1)where n represents the number of electrons in the valence shell of the atom and r,the covalent radius in Angstrms.The new scale is related to Pauling's electronegativity by the following equation: Χ_(Pauling)=a n/r+b (2) where a=0.34,b=0.67. The electronegativities of most elements in various valence states have been calculated and the values found are close to those obtained by other authors.

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Available abstract

In this paper,a new electronegativity scale is proposed in terms of the atomic petcntial Χ,namely,Χ=n/r (1)where n represents the number of electrons in the valence shell of the atom and r,the covalent radius in Angstrms.The new scale is related to Pauling's electronegativity by the following equation: Χ_(Pauling)=a n/r+b (2) where a=0.34,b=0.67. The electronegativities of most elements in various valence states have been calculated and the values found are close to those obtained by other authors.

Key concepts: Electronegativity, Chemistry, Formal charge, Valence electron, Valence (chemistry), Atomic radius, Atom (system on chip), Electron

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