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ON THE RELATIONSHIP BETWEEN ELECTRONEGATIVITY AND SOME PARAMETERS OF ATOMIC STRUCTURE

N Chen

Open publisher page 1 citations

Abstract

This paper deals with She physical and philosophical concepts of electronegativity. Some diagrammatic methods, using the Charge-radius ratio and electronegativity as parameters, are described. It appears that the electronegativity scale, which often fails when used alone, can be applied to solve some practical problems successfully when it is used in combination with the charge-radius ratio. The relationship of electronegativity scale to the charge-radius ratio and some other parameters describing the radial distribution of inner electrons, such as R_0/γ_(cov). and ρ (γ_(cov.)), has been investigated. Some empirical equations are proposed, and the physical meaning of the relationship is discussed.

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What this paper is about

This paper deals with She physical and philosophical concepts of electronegativity. Some diagrammatic methods, using the Charge-radius ratio and electronegativity as parameters, are described. It appears that the electronegativity scale, which often fails when used alone, can be applied to solve some practical problems successfully when it is used in combination with the charge-radius ratio. The relationship of electronegativity scale to the charge-radius ratio and some other parameters describing the radial distribution of inner electrons, such as R_0/γ_(cov). and ρ (γ_(cov.)), has been investigated. Some empirical equations are proposed, and the physical meaning of the relationship is discussed.

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Available abstract

This paper deals with She physical and philosophical concepts of electronegativity. Some diagrammatic methods, using the Charge-radius ratio and electronegativity as parameters, are described. It appears that the electronegativity scale, which often fails when used alone, can be applied to solve some practical problems successfully when it is used in combination with the charge-radius ratio. The relationship of electronegativity scale to the charge-radius ratio and some other parameters describing the radial distribution of inner electrons, such as R_0/γ_(cov). and ρ (γ_(cov.)), has been investigated. Some empirical equations are proposed, and the physical meaning of the relationship is discussed.

Key concepts: Electronegativity, Atomic radius, Formal charge, Chemistry, RADIUS, Charge (physics), Scale (ratio), Effective nuclear charge

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