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Adsorption Behavior of D301 Resin for Reactive Deep Blue K-R

Wang Quan-xi, Menglin Chen, HE Xing-cun, Zhi Fang Huang, Xiangfeng Lin

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Abstract

The adsorption property of reactive deep blue K-R on D301 resin is studied.A well fitted Freundlich equation is obtained for the adsorption isotherm within the observed temperature and concentration range,which indicates an endothermic and a favorable adsorption.The results of the enthalpy of adsorption,free energy,and entropy of adsorption indicate that : the positive value of △H shows an endothermic process,and the negative value of △G shows the spontaneous nature of the adsorption process,and the positive value of △S indicates the increased randomness at the solid/solution interface during the adsorption process.The kinetic study shows that the adsorption process is under the control of intra-particle diffusion and other diffusions simultaneously.

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What this paper is about

The adsorption property of reactive deep blue K-R on D301 resin is studied.A well fitted Freundlich equation is obtained for the adsorption isotherm within the observed temperature and concentration range,which indicates an endothermic and a favorable adsorption.The results of the enthalpy of adsorption,free energy,and entropy of adsorption indicate that : the positive value of △H shows an endothermic process,and the negative value of △G shows the spontaneous nature of the adsorption process,and the positive value of △S indicates the increased randomness at the solid/solution interface during the adsorption process.The kinetic study shows that the adsorption process is under the control of intra-particle diffusion and other diffusions simultaneously.

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Available abstract

The adsorption property of reactive deep blue K-R on D301 resin is studied.A well fitted Freundlich equation is obtained for the adsorption isotherm within the observed temperature and concentration range,which indicates an endothermic and a favorable adsorption.The results of the enthalpy of adsorption,free energy,and entropy of adsorption indicate that : the positive value of △H shows an endothermic process,and the negative value of △G shows the spontaneous nature of the adsorption process,and the positive value of △S indicates the increased randomness at the solid/solution interface during the adsorption process.The kinetic study shows that the adsorption process is under the control of intra-particle diffusion and other diffusions simultaneously.

Key concepts: Adsorption, Endothermic process, Chemistry, Freundlich equation, Exothermic reaction, Enthalpy, Thermodynamics, Diffusion

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