2008•Journal of Hubei Institute for NationalitiesRequires access

Preparation of Cellulose Triphenylcarbamate Used as Chiral Stationary Phases for the Separation of Enantiomers

Li‐Ming Yuan

Abstract

Cellulose triphenylcarbamate(CTPC) were synthesized,and coated to 3-aminopropyl silica gel.Their optical resolution abilities as chiral stationary phase(CSPs) were evaluated for high-performance liquid chromatography(HPLC).14 chiral compounds were resolved on the CSPs in the normal phase,and 8 chiral compounds could be separated.The CTPC CSPs show an excellent ability of resolving chiral compounds.

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Key concepts: Enantiomer, Chiral stationary phase, High-performance liquid chromatography, Cellulose, Chiral derivatizing agent, Chiral column chromatography, Chromatography, Silica gel