Reaction Study of Dibromo-tropolone and Aryl-hydrazine,Hydrazine Hydrate,Hydroxylamine and NaN_3
Wentao Gao
Abstract
Wentao Gao
Abstract
3-acetyltropolone was substituted by bromine at ice-water temperature in the presence of acetic acid to give 3-acetyl-5,7-dibromotroplone(1).Then compound(1) was reacted with aryl-hydrazine,hydrazine hydrate,hydroxylamine and NaN3,respectively to get compounds 2a-d,3,4 and 5.The purities of the compounds were within 91.7-100%.And the structures of the compounds were confirmed by IR,HNMR,MS data.
A significance statement is not available in the OpenAlex record.
A contribution statement is not available in the OpenAlex record.
Method details are not available in the OpenAlex metadata.
Findings are not separately available in the OpenAlex metadata.
Limitations are not available in the OpenAlex metadata.
Application details are not available in the OpenAlex metadata.
3-acetyltropolone was substituted by bromine at ice-water temperature in the presence of acetic acid to give 3-acetyl-5,7-dibromotroplone(1).Then compound(1) was reacted with aryl-hydrazine,hydrazine hydrate,hydroxylamine and NaN3,respectively to get compounds 2a-d,3,4 and 5.The purities of the compounds were within 91.7-100%.And the structures of the compounds were confirmed by IR,HNMR,MS data.
Key concepts: Hydrazine (antidepressant), Hydrate, Hydroxylamine, Chemistry, Tropolone, Bromine, Acetic acid, Aryl