2010Chemical Research and ApplicationRequires access

Preparation and characterization of Co doped SO_4~(2-)/SnO_2 solid superacid

Yan Peng

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Abstract

Solid superacid SO42-/SnO2 was modified by Co via impregnation and deposition method.The catalytic performance of the prepared superacid catalyst was evaluated by esterification of acetic acid and n-butanol,The results showed the existence of Co significantly improved the catalytic activity of solid superacid,when calcining temperature was 500℃,the catalyst had the highest activity.Furthermore,the physicochemical properties of the materials were characterized by FT IR,XRD,and TG-DTA.

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What this paper is about

Solid superacid SO42-/SnO2 was modified by Co via impregnation and deposition method.The catalytic performance of the prepared superacid catalyst was evaluated by esterification of acetic acid and n-butanol,The results showed the existence of Co significantly improved the catalytic activity of solid superacid,when calcining temperature was 500℃,the catalyst had the highest activity.Furthermore,the physicochemical properties of the materials were characterized by FT IR,XRD,and TG-DTA.

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Available abstract

Solid superacid SO42-/SnO2 was modified by Co via impregnation and deposition method.The catalytic performance of the prepared superacid catalyst was evaluated by esterification of acetic acid and n-butanol,The results showed the existence of Co significantly improved the catalytic activity of solid superacid,when calcining temperature was 500℃,the catalyst had the highest activity.Furthermore,the physicochemical properties of the materials were characterized by FT IR,XRD,and TG-DTA.

Key concepts: Superacid, Catalysis, Calcination, Acetic acid, Materials science, Inorganic chemistry, Chemistry, Nuclear chemistry

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