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1999•Chinese Journal of Structural ChemistryRequires access

Synthesis and Studies on the Non isothermal Kinetics of Thermal Decomposition of Complex Zn(C_9H_6O_5N_2)·2H_2O

Feng Shi

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Abstract

The complex Zn(C 9H 6O 5N 2)·2H 2O was prepared, its structure was assigned on the basis of element analysis, IR, moler conductance. And its kinetics of thermal decomposition was studied under non isothermal condition with TG. The possible equation of non isothermal kinetics at third step is suggested by the Achar method and the coats Redfern method and the new method. The kinetic equation may be expressed: d α /d t= Ae -E/RT (1-α )

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What this paper is about

The complex Zn(C 9H 6O 5N 2)·2H 2O was prepared, its structure was assigned on the basis of element analysis, IR, moler conductance. And its kinetics of thermal decomposition was studied under non isothermal condition with TG. The possible equation of non isothermal kinetics at third step is suggested by the Achar method and the coats Redfern method and the new method. The kinetic equation may be expressed: d α /d t= Ae -E/RT (1-α )

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Available abstract

The complex Zn(C 9H 6O 5N 2)·2H 2O was prepared, its structure was assigned on the basis of element analysis, IR, moler conductance. And its kinetics of thermal decomposition was studied under non isothermal condition with TG. The possible equation of non isothermal kinetics at third step is suggested by the Achar method and the coats Redfern method and the new method. The kinetic equation may be expressed: d α /d t= Ae -E/RT (1-α )

Key concepts: Chemistry, Isothermal process, Kinetics, Thermal decomposition, Decomposition, Thermodynamics, Kinetic energy, Conductance

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