Distribution and Leaching Characteristics of Heavy Metals in MSWI Fly Ash
Zhang Zheng-an
Abstract
Zhang Zheng-an
Abstract
Distribution of heavy metals in municipal solid waste incinerator(MSWI)fly ash was investigated by means of particle size and leaching procedures.Results showed that most of fly ash was accumulated in fractions with particle size of 38~280μm and fractions of 38~53μm accounted for about 50%.Besides Ni and Cr,other metals including Zn,Cd,Cu and Pb were mainly accumulated in fine fractions.The amount of Cr,Ni,Cu and Cd that leached out from fly ash samples increased with the decrease of particle size of fractions,while amount of Zn and Pb that leached out presented a rapid increase in 106~280μm and 75~106μm.Chemical speciation distribution of heavy metals was distinctly different according to results from sequential extraction procedure,and the most heavy metals were presented in the unstable speciation except of Ni and Cr.
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Distribution of heavy metals in municipal solid waste incinerator(MSWI)fly ash was investigated by means of particle size and leaching procedures.Results showed that most of fly ash was accumulated in fractions with particle size of 38~280μm and fractions of 38~53μm accounted for about 50%.Besides Ni and Cr,other metals including Zn,Cd,Cu and Pb were mainly accumulated in fine fractions.The amount of Cr,Ni,Cu and Cd that leached out from fly ash samples increased with the decrease of particle size of fractions,while amount of Zn and Pb that leached out presented a rapid increase in 106~280μm and 75~106μm.Chemical speciation distribution of heavy metals was distinctly different according to results from sequential extraction procedure,and the most heavy metals were presented in the unstable speciation except of Ni and Cr.
Key concepts: Fly ash, Leaching (pedology), Heavy metals, Chemistry, Environmental chemistry, Particle size, Particle-size distribution, Incineration