1998Journal of University of Science and Technology BeijingRequires access

Successive Determination of Ba and Sr by Spectrophotometrywith Dibromomethyl Carboxyazo

Ust Beijing

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Abstract

The colour reactions of barium (Ⅱ) and strontium (Ⅱ) with dibromomethyl carboxyazo were studied comparatively. In the medium of H3 PO4, the colour reaction of barium (Ⅱ) is highly selectivity and tolerates the existence of 6 - fold of strontium(Ⅱ). And in the buffer medium of H3BO3 - Na2B4O7,the absorbances of colour coordination compounds for barium(Ⅱ) and strontium(Ⅱ) have an additivity over a certain range of concentrtion.On these grounds, a new method of the successive determination for barium and strontium had been developed.

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What this paper is about

The colour reactions of barium (Ⅱ) and strontium (Ⅱ) with dibromomethyl carboxyazo were studied comparatively. In the medium of H3 PO4, the colour reaction of barium (Ⅱ) is highly selectivity and tolerates the existence of 6 - fold of strontium(Ⅱ). And in the buffer medium of H3BO3 - Na2B4O7,the absorbances of colour coordination compounds for barium(Ⅱ) and strontium(Ⅱ) have an additivity over a certain range of concentrtion.On these grounds, a new method of the successive determination for barium and strontium had been developed.

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Available abstract

The colour reactions of barium (Ⅱ) and strontium (Ⅱ) with dibromomethyl carboxyazo were studied comparatively. In the medium of H3 PO4, the colour reaction of barium (Ⅱ) is highly selectivity and tolerates the existence of 6 - fold of strontium(Ⅱ). And in the buffer medium of H3BO3 - Na2B4O7,the absorbances of colour coordination compounds for barium(Ⅱ) and strontium(Ⅱ) have an additivity over a certain range of concentrtion.On these grounds, a new method of the successive determination for barium and strontium had been developed.

Key concepts: Strontium, Barium, Selectivity, Chemistry, Inorganic chemistry, Mineralogy, Organic chemistry, Catalysis

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