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KINETIC STUDIES OF Cu(II)-EDTA-HCHO ELECTROLESS COPPER PLATING SYSTEM

Minghui Tan, Maotian Xu

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Abstract

The kinetic behavior of the cathodic reaction and the anodic reaction during Cu(II)-EDTA-HOHO electroless copper plating has been investigated. The dependence of surface concentration of CuEDTA2-, which is reduced to form copper and covered on specimen, on plating time has been determined. The values of stable plating rate calculated from the equation expressing the relation between the stable plating rate and the equilibrium surface concentration of OuEDTA2-are quite consistent with the corresponding measured values. Finally the actual reaction order of electroless copper plating has also been obtained.

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The kinetic behavior of the cathodic reaction and the anodic reaction during Cu(II)-EDTA-HOHO electroless copper plating has been investigated. The dependence of surface concentration of CuEDTA2-, which is reduced to form copper and covered on specimen, on plating time has been determined. The values of stable plating rate calculated from the equation expressing the relation between the stable plating rate and the equilibrium surface concentration of OuEDTA2-are quite consistent with the corresponding measured values. Finally the actual reaction order of electroless copper plating has also been obtained.

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Available abstract

The kinetic behavior of the cathodic reaction and the anodic reaction during Cu(II)-EDTA-HOHO electroless copper plating has been investigated. The dependence of surface concentration of CuEDTA2-, which is reduced to form copper and covered on specimen, on plating time has been determined. The values of stable plating rate calculated from the equation expressing the relation between the stable plating rate and the equilibrium surface concentration of OuEDTA2-are quite consistent with the corresponding measured values. Finally the actual reaction order of electroless copper plating has also been obtained.

Key concepts: Copper, Copper plating, Plating (geology), Electroless plating, Cathodic protection, Anode, Chemistry, Kinetic energy

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