Intrinsic kinetics of CO shift reaction over BX HTS catalyst

This paper described the intrinsic kinetic behavior of CO high temperature shift(HTS) reaction under atmospheric pressure over BX catalyst in an isothermal integral reactor.Under the condition simulating industrial operation,experiments were carried out by means of orthomorphic list experimental designing.Power type intrinsic rate model of the shift reaction were determined by non linear least square parameter estimation method.Accuracy of the experimental data and mathematic model was proved through F examination,correlation coefficient ρ 2 examination and calculation of catalyst quantity of an industrial shift reactor.