Synthesis and Crystal Structure of A Novel Porous Coordination Polymer [La(C_8H_6NO_2)_3]_n
Qiusheng Zhou
Abstract
Qiusheng Zhou
Abstract
A novel porous coordination polymer [La(C8H6NO2)3]n was synthesized by hydrothermal reaction of flexible ligands 3 (3 pyridyl)acrylate and La(NO3)3· 6H2O. The structure was characterized by elemental analysis, IR spectroscopy and X ray single crystal diffraction. X ray single crystal analysis reveals the structure consists of [La(C8H6NO2)3]n. It crystallizes in monoclinic crystal system with space group P2(1)/c. Crystallographic date: a=0. 7889(3)nm, b=2.5916(9)nm, c=1.1489(4)nm, α =90.00° , β =95.219(6)° , γ =90.00° , V=2.3393(15)nm3, Z=4, Dc=1.656g· cm- 3, μ =1.871mm- 1, F(000)=1152, R1=0.0328, wR2=0.0522. CCDC: 211700.
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A novel porous coordination polymer [La(C8H6NO2)3]n was synthesized by hydrothermal reaction of flexible ligands 3 (3 pyridyl)acrylate and La(NO3)3· 6H2O. The structure was characterized by elemental analysis, IR spectroscopy and X ray single crystal diffraction. X ray single crystal analysis reveals the structure consists of [La(C8H6NO2)3]n. It crystallizes in monoclinic crystal system with space group P2(1)/c. Crystallographic date: a=0. 7889(3)nm, b=2.5916(9)nm, c=1.1489(4)nm, α =90.00° , β =95.219(6)° , γ =90.00° , V=2.3393(15)nm3, Z=4, Dc=1.656g· cm- 3, μ =1.871mm- 1, F(000)=1152, R1=0.0328, wR2=0.0522. CCDC: 211700.
Key concepts: Monoclinic crystal system, Crystal structure, Crystallography, Coordination polymer, Single crystal, Materials science, Hydrothermal circulation, Hydrothermal synthesis