2009Gōsei jushiRequires access

Structure Transformation of Polypropylene and the Change of Mechanical Properties of Polypropylene Induced by UV Light

Xin Qian

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Abstract

The effects of UV irradiation on the morphologic,mechanical properties and surface structure of α-nucleated PP(α-PP),β-nucleated PP(β-PP)and neat PP were studied.The lower degradability was found in β-PP as compared to α-PP and neat PP.An increase in crystallinity on short-time exposure followed by crystallinity decreased with prolonged exposure was detected in all samples.The β-phase content in the crystallinity portion of β-PP increased on short-time exposure,followed by crystallinity decreased with prolonged exposure,α-phase content of β-PP increased after shot-time decreased,then remained constant after 312 h exposure.

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What this paper is about

The effects of UV irradiation on the morphologic,mechanical properties and surface structure of α-nucleated PP(α-PP),β-nucleated PP(β-PP)and neat PP were studied.The lower degradability was found in β-PP as compared to α-PP and neat PP.An increase in crystallinity on short-time exposure followed by crystallinity decreased with prolonged exposure was detected in all samples.The β-phase content in the crystallinity portion of β-PP increased on short-time exposure,followed by crystallinity decreased with prolonged exposure,α-phase content of β-PP increased after shot-time decreased,then remained constant after 312 h exposure.

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Available abstract

The effects of UV irradiation on the morphologic,mechanical properties and surface structure of α-nucleated PP(α-PP),β-nucleated PP(β-PP)and neat PP were studied.The lower degradability was found in β-PP as compared to α-PP and neat PP.An increase in crystallinity on short-time exposure followed by crystallinity decreased with prolonged exposure was detected in all samples.The β-phase content in the crystallinity portion of β-PP increased on short-time exposure,followed by crystallinity decreased with prolonged exposure,α-phase content of β-PP increased after shot-time decreased,then remained constant after 312 h exposure.

Key concepts: Crystallinity, Polypropylene, Materials science, Phase (matter), Irradiation, Composite material, Polymer chemistry, Chemistry

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