1986Ganguang kexue yu guanghuaxueRequires access

STUDY ON TRIPLE EXCIPLEX

S Chen

Open publisher page 0 citations

Abstract

In this paper, it was demonstrated that the interaction of excited acenaphthene with 1,4-dicyanobenzene will lead to the formation of exciplex and triple exciplex. The latter will be formed at higher concentration of acenaphthene. In the case of polyacenaph-thylene, intramolecular excimer could be formed between nonadjacent chromophores. As a result of interaction of excited polyacenaphthylene and 1,4-dicyanobenzene, triple exciplex can be formed too. The mechanism of the formation of triple exciplex was proofed as exciplex→ triple exciplex but not excimer→ triple exciplex.

About this research paper

What this paper is about

In this paper, it was demonstrated that the interaction of excited acenaphthene with 1,4-dicyanobenzene will lead to the formation of exciplex and triple exciplex. The latter will be formed at higher concentration of acenaphthene. In the case of polyacenaph-thylene, intramolecular excimer could be formed between nonadjacent chromophores. As a result of interaction of excited polyacenaphthylene and 1,4-dicyanobenzene, triple exciplex can be formed too. The mechanism of the formation of triple exciplex was proofed as exciplex→ triple exciplex but not excimer→ triple exciplex.

Why it matters

A significance statement is not available in the OpenAlex record.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

In this paper, it was demonstrated that the interaction of excited acenaphthene with 1,4-dicyanobenzene will lead to the formation of exciplex and triple exciplex. The latter will be formed at higher concentration of acenaphthene. In the case of polyacenaph-thylene, intramolecular excimer could be formed between nonadjacent chromophores. As a result of interaction of excited polyacenaphthylene and 1,4-dicyanobenzene, triple exciplex can be formed too. The mechanism of the formation of triple exciplex was proofed as exciplex→ triple exciplex but not excimer→ triple exciplex.

Key concepts: Excimer, Excited state, Acenaphthene, Photochemistry, Chromophore, Chemistry, Intramolecular force, Fluorescence

Related papers

Back to paper searchBrowse research topicsOriginal source
STUDY ON TRIPLE EXCIPLEX — Research Paper | ScholarLens