STUDY ON TRIPLE EXCIPLEX
S Chen
Abstract
S Chen
Abstract
In this paper, it was demonstrated that the interaction of excited acenaphthene with 1,4-dicyanobenzene will lead to the formation of exciplex and triple exciplex. The latter will be formed at higher concentration of acenaphthene. In the case of polyacenaph-thylene, intramolecular excimer could be formed between nonadjacent chromophores. As a result of interaction of excited polyacenaphthylene and 1,4-dicyanobenzene, triple exciplex can be formed too. The mechanism of the formation of triple exciplex was proofed as exciplex→ triple exciplex but not excimer→ triple exciplex.
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In this paper, it was demonstrated that the interaction of excited acenaphthene with 1,4-dicyanobenzene will lead to the formation of exciplex and triple exciplex. The latter will be formed at higher concentration of acenaphthene. In the case of polyacenaph-thylene, intramolecular excimer could be formed between nonadjacent chromophores. As a result of interaction of excited polyacenaphthylene and 1,4-dicyanobenzene, triple exciplex can be formed too. The mechanism of the formation of triple exciplex was proofed as exciplex→ triple exciplex but not excimer→ triple exciplex.
Key concepts: Excimer, Excited state, Acenaphthene, Photochemistry, Chromophore, Chemistry, Intramolecular force, Fluorescence