Thermoanalysis experimental study on rich-silica belite aluminosulphate cement
Zhang Ju
Abstract
Zhang Ju
Abstract
Richsilica belite aluminosulphate cement burned in the temperature of 1?200℃ in rough has higher strength than that burned in higher temperature. In order to look into the causes of this phenomenon, thermoanalysis of CaSO3·2H2O, CA,C4A3,C2S,C4AF and richsilica belite aluminosulphate cement are done on the basis of XRD analysis of document[1,2]. When the burning temperature of cement is below 1?200℃,C2S and C4A3 is not formed in large quantity and chemical combination rate of gypsum is only 4%, therefore the strength of cement is low. When the burning temperature of cement is above 1?250℃, gypsum begins to decompose and the decomposing rate of CaSO3·2H2O,C4A3 and richsilica belite aluminosulphate cement is 8%, 305% and 2668% respectively, which is not beneficial to the stable existence of C4A3, and even leads to the decomposing of C4A3 and lowers the cement strength eventually.
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Richsilica belite aluminosulphate cement burned in the temperature of 1?200℃ in rough has higher strength than that burned in higher temperature. In order to look into the causes of this phenomenon, thermoanalysis of CaSO3·2H2O, CA,C4A3,C2S,C4AF and richsilica belite aluminosulphate cement are done on the basis of XRD analysis of document[1,2]. When the burning temperature of cement is below 1?200℃,C2S and C4A3 is not formed in large quantity and chemical combination rate of gypsum is only 4%, therefore the strength of cement is low. When the burning temperature of cement is above 1?250℃, gypsum begins to decompose and the decomposing rate of CaSO3·2H2O,C4A3 and richsilica belite aluminosulphate cement is 8%, 305% and 2668% respectively, which is not beneficial to the stable existence of C4A3, and even leads to the decomposing of C4A3 and lowers the cement strength eventually.
Key concepts: Belite, Cement, Gypsum, Materials science, Metallurgy, Mineralogy, Chemical engineering, Clinker (cement)