2005•Chinese Journal of Applied ChemistryRequires access

Synthesis and Recognization Property of Sulfamethazine Molecularly Imprinted Polymer

Hui Liu

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Abstract

Molecularly imprinted polymers(MIPs) of sulfamethazine(SM 2 ) were prepared with silica gel as a sacrificial material, methacrylic acid(MAA) and 4 vinylpyridine(4 Vp) as functional monomers, glycol dimethacrylate(EDMA) as crosslinker. The polymer properties were investigated by static adsorption experiments. Scatchard analysis shows that the adsorption ability of MAA MIP is superior to that of 4 Vp MIP. The dissociation constant of MAA MIP is 9 59×10 -4 mol/L. The value of apparent binding ability is 307 0 μmol/g.

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What this paper is about

Molecularly imprinted polymers(MIPs) of sulfamethazine(SM 2 ) were prepared with silica gel as a sacrificial material, methacrylic acid(MAA) and 4 vinylpyridine(4 Vp) as functional monomers, glycol dimethacrylate(EDMA) as crosslinker. The polymer properties were investigated by static adsorption experiments. Scatchard analysis shows that the adsorption ability of MAA MIP is superior to that of 4 Vp MIP. The dissociation constant of MAA MIP is 9 59×10 -4 mol/L. The value of apparent binding ability is 307 0 μmol/g.

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Available abstract

Molecularly imprinted polymers(MIPs) of sulfamethazine(SM 2 ) were prepared with silica gel as a sacrificial material, methacrylic acid(MAA) and 4 vinylpyridine(4 Vp) as functional monomers, glycol dimethacrylate(EDMA) as crosslinker. The polymer properties were investigated by static adsorption experiments. Scatchard analysis shows that the adsorption ability of MAA MIP is superior to that of 4 Vp MIP. The dissociation constant of MAA MIP is 9 59×10 -4 mol/L. The value of apparent binding ability is 307 0 μmol/g.

Key concepts: Chemistry, Molecularly imprinted polymer, Methacrylic acid, Adsorption, Dissociation constant, Polymer, Ethylene glycol dimethacrylate, Molecular imprinting

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